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. Author manuscript; available in PMC: 2015 Oct 21.
Published in final edited form as: J Am Chem Soc. 2015 May 19;137(22):7111–7121. doi: 10.1021/jacs.5b00498

Figure 6.

Figure 6

13C Mims ENDOR for LAM with [13C-methyl]-anSAM, PLP and substrate with simulation spectrum. Spectrum collected at radical peak. Experimental conditions: MF = 34.74 GHz, MW pulse length (π/2) = 50 ns, τ = 400 ns for Mims, and T = 2 K. Simulations (blue) with ENDOR line-widths of 0 and 0.28 MHz; parameters, Aiso = −0.61 MHz, T = 0.21 MHz (distance r = 3.6 Å).