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. 2015 Oct 23;5:15664. doi: 10.1038/srep15664

Table 1. Hydrogenation of resorcinol over Pd catalysts in CH2Cl2 solvent.

Entry Catalysts T (°C) PH2(MPa) Time (h) RES Con. (%) 1,3-CHD Sel. (%)
1 Pd/rGO 20 0.1 3 84.0 100
2 Pd/rGO 25 0.5 3 99.9 93.2
3 Pd/rGO 25 1 1 95.1 99.9
        3 99.9 94.2
4 Pd/rGO 30 0.5 1 83 90.7
        2 92.1 87.1
        3 99.9 85.1
5 Pd/rGO 40 0.5 0.5 70.6 86.2
        1 99.9 83.5
6 Pd/rGO 40 2 0.5 99.9 54.5
7a Pd/rGO 25 1 3 99.9 93.8
8 Pd/AC 25 1 1 99.9 26.6
9 Pd/SiO2 25 1 3 99.9 21.2
10 Pd/MWCNT 25 1 3 99.9 52.3

Reaction conditions: resorcinol (0.027 mmol), CH2Cl2 solvent (3 ml), 50 mg of Pd catalyst with 3 wt% Pd loading. aThe 5th reuse of Pd/rGO.