Table 5. Catalyst stability screen a .
Entry | Catalyst | Conditions | t 1/2 |
1 |
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(a) Solid rt | 15 days |
(b) Solid –20 °C | 8 months | ||
(c) HCl salt, rt | >5 years | ||
(d) 0.035 M PhMe | 7 h | ||
2 |
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Solid, rt | 16 h |
3 |
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Solid, rt | 5 months |
4 |
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(a) Solid, rt | >5 years |
(b) 0.035 M | 36 h | ||
5 |
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(a) Solid, rt | 12 h |
(b) 0.035 M | 3 h |
aDecomposition monitored by 1H NMR; see ESI for method used for each cyclopropenimine.