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. 2014 Dec 19;6(2):1537–1547. doi: 10.1039/c4sc02402h

Table 5. Catalyst stability screen a .

Entry Catalyst Conditions t 1/2
1 graphic file with name c4sc02402h-u16.jpg (a) Solid rt 15 days
(b) Solid –20 °C 8 months
(c) HCl salt, rt >5 years
(d) 0.035 M PhMe 7 h
2 graphic file with name c4sc02402h-u17.jpg Solid, rt 16 h
3 graphic file with name c4sc02402h-u18.jpg Solid, rt 5 months
4 graphic file with name c4sc02402h-u19.jpg (a) Solid, rt >5 years
(b) 0.035 M 36 h
5 graphic file with name c4sc02402h-u20.jpg (a) Solid, rt 12 h
(b) 0.035 M 3 h

aDecomposition monitored by 1H NMR; see ESI for method used for each cyclopropenimine.