Table 6.
Peak number(b) | Compounds(c) | Retention time (min) | Peak area ×103 | |
---|---|---|---|---|
A. princeps | Seomae mugwort | |||
1 | Propanoic acid methyl ester | 3.32 | 4,655.5 ± 502.1b | 43,759.7 ± 1,202.3a |
2 | Acetic acid ethyl ester | 3.91 | 873.6 ± 90.2b | 8,365.1 ± 902.1a |
3 | 2,3-Dimethyl pentane | 4.79 | 89.1 ± 84.3b | 984.5 ± 42.5a |
4 | Butyl ethyl ether | 5.39 | 478.3 ± 63.1b | 4,321.9 ± 472.5a |
5 | Diethyl sulfide | 5.51 | 61.5 ± 33.2b | 1,687.2 ± 202.9a |
6 | Acetal | 6.29 | 1,122.9 ± 172.6b | 13,265.2 ± 1,502.5a |
7 | 2-Methyl-2-hexanol | 6.98 | Not detectedb | 1,178.4 ± 227.3a |
8 | Valeric acid methylbutyl ester | 7.07 | 1,646.2 ± 216.2b | 19,573.6 ± 1,312.4a |
9 | Methylbenzene | 7.32 | 372.7 ± 39.3b | 3,455.6 ± 482.1a |
10 | 2-Furancarboxaldehyde | 9.45 | 53.3 ± 32.1b | 953.3 ± 113.2a |
11 | Chlorobenzene | 9.87 | 59.5 ± 29.6b | 757.16 ± 221.5a |
12 | 2-Hexenal | 10.13 | Not detectedb | 1,323.3 ± 160.5a |
13 | Ethyl benzene | 10.40 | 1,253.9 ± 264.3b | 15,135.1 ± 1,302.1a |
14 | m-Xylol | 10.67 | 42.9 ± 40.7b | 624.01 ± 129.4a |
15 | o-Xylol | 11.47 | 89.3 ± 66.2b | 1,628.5 ± 278.4a |
16 | α-Terpinolene | 12.62 | Not detectedb | 60,468.9 ± 2,532.8a |
17 | α-Pinene | 12.85 | 252.9 ± 102.5b | 5,512.4 ± 762.0a |
18 | Camphene | 13.35 | Not detectedb | 2,842.3 ± 388.7a |
19 | Sabinene | 14.18 | 49.8 ± 36.1b | 357.3 ± 94.4a |
20 | β-Pinene | 14.29 | 220.3 ± 100.5b | 1,473.5 ± 233.5a |
21 | 1-Octen-3-ol | 14.34 | Not detected | 3,433.3 ± 582.3a |
22 | β-Myrcene | 14.72 | 119.4 ± 84.5a | Not detectedb |
23 | Yomogi alcohol | 15.08 | Not detectedb | 288,651.3 ± 1,321.1a |
24 | α-Terpinene | 15.57 | Not detectedb | 1,863.8 ± 282.4a |
25 | o-Cymene | 15.83 | Not detectedb | 1,483.3 ± 248.5a |
26 | D-Limonene | 15.96 | 75.9 ± 63.1b | 750.3 ± 121.5a |
27 | 1,8-Cineole | 16.05 | Not detectedb | 32,351.2 ± 1,321.8a |
28 | 2,4-Hexadiene | 16.17 | Not detectedb | 5,933.3 ± 567.3a |
29 | Phenyloxirane | 16.42 | 695.1 ± 111.8a | Not detectedb |
30 | Benzeneacetaldehyde | 16.43 | Not detectedb | 5,493.2 ± 484.3a |
31 | γ-Terpinene | 16.90 | Not detectedb | 1,384.6 ± 233.2a |
32 | cis-β-Terpineol | 17.21 | Not detectedb | 617.9 ± 171.3a |
33 | Artemisia alcohol | 17.78 | Not detectedb | 533,734.3 ± 8,242.0a |
34 | β-Linalool | 18.15 | 136.7 ± 70.3b | 17,562.3 ± 1,382.4a |
35 | Nonanal | 18.25 | 80.7 ± 29.5a | Not detectedb |
36 | Camphor | 19.57 | Not detectedb | 4,463.87 ± 529.4a |
37 | 4-Terpineol | 20.49 | Not detectedb | 4,215.52 ± 498.5a |
38 | β-Fenchyl alcohol | 20.88 | Not detectedb | 2,583.98 ± 200.4a |
39 | Indole | 23.69 | 144.0 ± 101.1b | 1,073.78 ± 218.3a |
40 | δ-Elemene | 24.87 | 75.4 ± 43.1a | Not detectedb |
41 | Eugenol | 25.34 | Not detectedb | 13,037.30 ± 1,009.3a |
42 | α-Copaene | 25.90 | 325.0 ± 112.2b | 2,643.10 ± 183.6a |
43 | β-Bourbone | 26.16 | 65.25 ± 45.6b | 2,933.01 ± 438.3a |
44 | β-Elemene | 26.27 | 845.4 ± 205.1a | Not detectedb |
45 | Caryophyllene | 27.06 | 13,728.3 ± 1,225.3b | 85,473.18 ± 5,384.5a |
46 | β-Copaene | 27.26 | Not detectedb | 1,417.52 ± 135.8a |
47 | α-Amorphene | 27.65 | 60.5 ± 60.9a | Not detectedb |
48 | cis-β-Farnesene | 27.75 | 1,890.6 ± 210.9b | 2,483.2 ± 499.3a |
49 | α-Humulene | 27.88 | 3,921.7 ± 673.3b | 9,065.3 ± 886.1a |
50 | γ-Muurolene | 28.37 | Not detectedb | 1,646.7 ± 245.3a |
51 | γ-Curcumene | 28.38 | 998.1 ± 89.0a | Not detectedb |
52 | β-Cubebene | 28.54 | 16,826.3 ± 1,533.2b | 29,434.57 ± 5,553.7a |
53 | β-Selinene | 28.68 | Not detectedb | 8,386.7 ± 1,334.3a |
54 | Zingiberene | 28.75 | 6,225.4 ± 562.1a | Not detectedb |
55 | Germacrene B | 28.91 | 1,347.8 ± 113.2a | Not detectedb |
56 | α-Farnesene | 28.99 | 889.5 ± 82.0a | Not detectedb |
57 | β-Bisabolene | 29.07 | 200.2 ± 121.2a | Not detectedb |
58 | γ-Cadinene | 29.29 | 353.5 ± 178.1b | 3,976.39 ± 529.9a |
59 | δ-Cadinene | 29.47 | 1,345.4 ± 203.1b | 4,073.7 ± 587.9a |
60 | α-Cadinene | 29.82 | 211.4 ± 52.2a | Not detectedb |
61 | trans-β-Farnesene | 30.33 | 158.2 ± 78.0a | Not detectedb |
62 | Nerolidol | 30.34 | Not detectedb | 3,122.5 ± 443.9a |
63 | Caryophyllene oxide | 30.95 | 315.3 ± 192.1a | Not detectedb |
64 | Diethyl phthalate | 31.02 | 233.6 ± 54.2a | Not detectedb |
65 | α-Guaiene | 31.30 | Not detectedb | 1,347.3 ± 309.4a |
66 | tau-Muurolol | 32.20 | 349.1 ± 120.2a | Not detectedb |
(a)Data represents the mean ± SD (n = 3). Different superscript letters indicate statistical significance of the differences between Seomae mugwort and A. princeps groups, tested by Student's t-test using the SAS. P values less than 0.05 were considered statistically significant. (b)Peak numbering was determined by the order of elution. (c)The gas chromatographic retention data and mass spectral data were compared to those of authentic samples and library compounds, respectively.