Table 1. Differential metabolites accountable for the discrimination between Cypermethrin exposed and control earthworms.
| ChEBI ID | Metabolite | Retention timein min | m/z ofanalyzedfragment | VIPscore | p-value | %Probability as perNIST library |
|---|---|---|---|---|---|---|
| CHEBI:6650 | Malic acida | 17.24 | 233 | 3.5351 | 3.5976E-21 | 76 |
| CHEBI:17234 | Glucosea | 24.82 | 319 | 2.9978 | 1.4334E-7 | 80 |
| CHEBI:16865 | GABAa | 17.92 | 174 | 2.6892 | 2.2749E-7 | 95 |
| CHEBI:16977 | Alaninea | 8.62 | 116 | 2.6865 | 5.3988E-19 | 82 |
| CHEBI:16000 | 2-Amino ethanol | 12.34 | 174 | 1.9224 | 1.1084E-9 | 84 |
| CHEBI:26078 | Phosphoric acid | 12.66 | 299 | 1.8769 | 2.4055E-15 | 79 |
| CHEBI:45919 | Tridecanoic acida | 21.29 | 271 | 1.7915 | 1.0114E-18 | 96 |
| CHEBI:28842 | Octadecanoic acida | 29.68 | 341 | 1.7256 | 9.1941E-8 | 97 |
| CHEBI:28875 | Tetradecanoic acida | 23.59 | 285 | 1.6296 | 1.5094E-15 | 98 |
| CHEBI:32365 | Heptadecanoic acida | 26.77 | 313 | 1.6275 | 8.3413E-10 | 98 |
| CHEBI:15603 | Leucinea | 12.49 | 158 | 1.6092 | 1.4199E-20 | 82 |
| CHEBI:17191 | Isoleucinea | 12.99 | 158 | 1.2819 | 3.1524E-12 | 75 |
| CHEBI:18183 | Pyroglutamic acid | 17.80 | 156 | 1.4898 | 5.4772E-7 | 94 |
| CHEBI:16857 | Threoninea | 13.02 | 117 | 1.4005 | 7.5697E-7 | 97 |
| CHEBI:17115 | Serinea | 12.29 | 116 | 1.377 | 2.3006E-5 | 98 |
| CHEBI:15428 | Glycinea | 13.23 | 174 | 1.358 | 2.8989E-4 | 90 |
| CHEBI:17268 | Myoinositola | 27.00 | 318 | 1.2075 | 0.0023104 | 83 |
| CHEBI:17203 | Prolinea | 13.01 | 142 | 1.1408 | 5.7539E-7 | 79 |
| CHEBI:16196 | Oleic acida | 29.37 | 339 | 1.0632 | 1.0487E-7 | 86 |
| CHEBI:16414 | Valinea | 11.21 | 218 | 1.1618 | 6.2002E-24 | 81 |
| CHEBI:28260 | Galactosea | 24.95 | 147 | 1.5966 | 6.532E-19 | 80 |
| CHEBI:17306 | Lactosea | 35.23 | 361 | 1.2361 | 2.0949E-13 | 95 |
aIdentification was unequivocally confirmed by comparison of retention times and spectral data to the corresponding pure standards.