Table 1.
Compound | Solvent | a/nm | a/nm | Δλ b/nm | Φf c |
---|---|---|---|---|---|
1 | Toluene | 461 | 585 | 124 | 0.35 |
DCM | 458 | 704 | 246 | 0.38 | |
DMSO | 454 | 789 | 335 | 0.01 | |
1a | DMSO | 455 | 789 | 334 | 0.02 |
2 | DMSO | 308, 360, 463 | 652 | 199 | 0.02 |
H2O | 308, 361, 469 | 720 | 251 | 0.01 | |
2a | DMSO | 310, 353, 454 | 754 | 300 | 0.02 |
3 | Toluene | 449 | 591 | 142 | 0.31 |
DCM | 445 | 767 | 322 | 0.03 | |
3a | H2O | 449 | 648 | 199 | 0.03 |
3b | H2O | 450 | 662 | 212 | 0.05 |
Absorption and emission maxima ±1 nm;
Stokes shift ±2 nm;
fluorescence quantum yields ±10%