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Diversification pathways for methoxy amides 5b or 7b (a) dimethyl malonate, Et3N, TiCl4; (b) 2-trimethylsilyloxyfuran, TiCl4; (c) N-methylindole, TiCl4; (d) 1,3,5-trimethoxybenzene, SnCl4; (e) TiCl4; Et3N; (f) thiopheneboronic acid; BF3•OEt2 (g) TiCl4; trimethylsilyl allyl silane (h) TiCl4; PhCCMgCuBr.
