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Proposed Oxygen Activation Pathway for the H200C-HPCD Variant That Involves Conversion of a Ferric Superoxo Intermediate to a Distal-Protonated Hydroperoxo, Semiquinone Radical Intermediate via Inner-Sphere PCET. a In the ES complex and superoxo intermediate the substrate is protonated at OC1 (red superscript H).
