Table 2. 13C T 1 relaxation times for solid various PCXCs at ambient temperature*.
Entry | PCXC structure |
T1
(s) |
||||||
---|---|---|---|---|---|---|---|---|
C=O | C |
CH |
CH2 | CH3 | ||||
1 | 2 | 3 | ||||||
1 | Amorphous | 48 | 21 | — | 38 | — | 26 | 1.3 |
2 | (S)-enantiopure | 92 | 29 | — | 36 | — | 21 | 1.6 |
3 | Multiblock | 156 | 40 | 110 | 50 | 116 | 58 | 1.3 |
4 | Stereocomplexed | 223 | 42 | 165 | — | 150 | 81 | 1.6 |
*Measured with CPMAS NMR using the saturation recovery-based sequence.