Table 1. Photovoltaic parameters of DSSCs based on the photoanodes of radially oriented mesoporous TiO2 microspheres, bulk mesoporous TiO2, and commercial P25 after TiCl4 treatment [measured under AM 1.5 sunlight illumination (100 mW cm−2)].
Samples |
Voc (mV) |
Jsc (mA cm−2) |
FF (%) |
η (%) |
Adsorbed dye (×10−7 mol cm−2)* |
Mesoporous TiO2 microspheres |
751 | 22.9 | 70.6 | 12.1 | 2.13 |
Bulk mesoporous TiO2 | 759 | 15.8 | 63.1 | 7.6 | 1.45 |
P25 | 734 | 12.3 | 75.0 | 6.8 | 1.12 |
*Dye-adsorbed films with an area of ~10 cm2 were used for estimating the adsorbed dye concentration. The commercial N719 dye was first desorbed into a 0.1 M NaOH solution in water and ethanol [1:1 (v/v)], and the desorbed N719 dye concentration was then measured by using an ultraviolet-visible spectrophotometer.