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. 2015 Aug 14;1(7):e1500441. doi: 10.1126/sciadv.1500441

Table 1. The catalytic performance of CNT-supported metal nanoclusters.

Reaction conditions: 20 mg of catalysis, 2 wt % nanocluster loading, 57 μl (0.5 mmol) of styrene, 144 μl (1.5 mmol) of tert-butyl hydroperoxide (TBHP), 1.5 ml of ethanol, 65°C, 24 hours.

Selectivity (%)
Entry Catalyst Conversion (%)* Epoxide Benzaldehyde Other products
1 Au25/CNT 72.8 20.3 66.4 13.3
2 Ag44/CNT 43.6 6.1 92.6 1.3
3 Ag46Au24/CNT 68.2 1.2 96.3 2.5
4 Ag32Au12/CNT 69.7 57.6 37.6 4.8
5 CNT 31.7 30.5 55.62 13.88

*Conversion = (styrene converted)/(initial amount of styrene) × 100.

Determined by gas chromatography.