| Crystal data |
| Chemical formula |
[Ag4(CNO)4(C18H15P)4] |
|
M
r
|
1648.64 |
| Crystal system, space group |
Tetragonal, P
|
| Temperature (K) |
110 |
|
a, c () |
24.0846(3), 15.2037(3) |
|
V (3) |
8819.2(3) |
|
Z
|
4 |
| Radiation type |
Mo K
|
| (mm1) |
0.99 |
| Crystal size (mm) |
0.35 0.30 0.20 |
| |
| Data collection |
| Diffractometer |
Oxford Gemini S diffractometer |
| Absorption correction |
Multi-scan (CrysAlis RED; Oxford Diffraction, 2006 ▸) |
|
T
min, T
max
|
0.912, 1.000 |
| No. of measured, independent and observed [I > 2(I)] reflections |
105239, 20082, 12667 |
|
R
int
|
0.048 |
| (sin /)max (1) |
0.674 |
| |
| Refinement |
|
R[F
2 > 2(F
2)], wR(F
2), S
|
0.045, 0.131, 1.01 |
| No. of reflections |
20082 |
| No. of parameters |
1018 |
| No. of restraints |
1206 |
| H-atom treatment |
H-atom parameters constrained |
|
max, min (e 3) |
0.68, 1.88 |
| Absolute structure |
Flack x determined using 5170 quotients [(I
+)(I
)]/[(I
+)+(I
)] (Parsons Flack, 2004 ▸) |
| Absolute structure parameter |
0.023(9) |
