Table 2. Experimental details.

Crystal data
Chemical formula	[Re2(C4H7O2)2Cl4(C2H6OS)2]
M r	844.65
Crystal system, space group	Monoclinic, P21/n
Temperature (K)	110
a, b, c ()	10.5581(4), 14.7406(5), 15.6088(6)
()	100.794(2)
V (3)	2386.26(15)
Z	4
Radiation type	Mo K
(mm1)	10.78
Crystal size (mm)	0.22 0.18 0.09
Data collection
Diffractometer	Siemens SMART CCD area-detector
Absorption correction	Multi-scan (SADABS; Bruker, 2008 ▸)
T min, T max	0.133, 0.478
No. of measured, independent and observed [I > 2(I)] reflections	93039, 14497, 11921
R int	0.040
(sin /)max (1)	0.909
Refinement
R[F 2 > 2(F 2)], wR(F 2), S	0.025, 0.049, 1.00
No. of reflections	14497
No. of parameters	243
H-atom treatment	H-atom parameters constrained
max, min (e 3)	1.71, 1.14

Computer programs: APEX2 and SAINT (Bruker, 2008 ▸), SHELXS97 (Sheldrick 2008 ▸), SHELXL2014 (Sheldrick, 2015 ▸), DIAMOND (Brandenburg, 1999 ▸) and WinGX (Farrugia, 2012 ▸).