Table 3.
Kinetic parameters of O2 release (slow phase) for WT and mutant thylakoid membranes
Ea (kJ·mol−1) | A (s−1) | tslow* (ms) | ΔSǂ (J·mol−1 K−1) | ΔHǂ (kJ·mol−1) | |
WT | 45.8 | 5.2 × 1010 | 1.1 | −47.1 | 43.7 |
V185N | 22.3 | 1.9 × 105 | 29.3 | −150.9 | 20.1 |
D61N | 44.2 | 1.5 × 109 | 22.9 | −77.4 | 41.8 |
D61A | 35.3 | 3.3 × 107 | 32.8 | −109.2 | 32.9 |
The uncertainties in the activation energies are of the order of ±2.
The values for the individual time constants are measured at 27 °C.