. Author manuscript; available in PMC: 2015 Nov 24.

Published in final edited form as: J Funct Foods. 2015 Aug;17:235–242. doi: 10.1016/j.jff.2015.05.016

Table 1. ¹³C NMR and ¹H NMR chemical shifts (δ in ppm) for cranf1b-F2.

Residue (Mol %)	Subunits	Linkages	C1/H1	C2/H2	C3/H3	C4/H4	C5/H5	C6/H6
Araf (56%)	Arabinan	t-α-Araf	107.69	81.56	77.17	84.58	61.75	-
	Arabinan	t-α-Araf	5.14	4.13	3.95	4.03	3.84	-
	Arabinan	3,5-α-Araf	108.11	79.83	82.90	82.11	67.14	-
	Arabinan	3,5-α-Araf	5.11	4.28	4.09	4.30	3.83/3.93	-
	Arabinan	5-α-Araf	108.15	81.53	77.25	83.02	66.89	-
	Arabinan	5-α-Araf	5.08	4.12	4.02	4.21	3.88/3.79	-
	Arabinan	3-α-Araf	107.72	80.26	84.33	83.09	-	-
	Arabinan	3-α-Araf	5.18	4.36	3.95	4.14	-	-
	S	t-α-Araf	109.87	81.66	77.05	84.44	61.81	-
	S	t-α-Araf	5.15	4.19	3.93	4.06	3.71	-

Xylp (14%)	S	2-α-Xylp	99.20	79.47	72.47	70.03	61.87	-
	S	2-α-Xylp	5.08	3.56	3.85	3.65	3.55	-
	L	2-α-Xylp	98.98	81.14	-	-	-	-
	L	2-α-Xylp	5.14	3.6	-	-	-	-
	X	t-α-Xylp	99.48	72.06	73.67	70.14	-	-
	X	t-α-Xylp	4.94	3.54	3.71	3.61	-	-

Galp (2%)	L	t-β-Galp	105.10	-	-	-	-	-
Galp (2%)	L	t-β-Galp	4.60-3.73	-	-	-	-	-

Glcp (27%)	_G	t-β-Glclp	105.24	-	-	-	-	-
	_G	t-β-Glclp	4.53	3.62	-	-	-	-
	G	4,6-β-Glcp	103.35	73.5	74.77	79.74	74.32	67.47
	G	4,6-β-Glcp	4.53	3.38	3.66	3.67	3.82	3.87/3.80
	G	4,6-β-Glcp	103.20	73.5	74.77	79.64	74.32	67.04
	G	4,6-β-Glcp	4.52	3.37	3.66	3.69	3.82	3.93/3.82
	G	4-β-Glcp	103.10	73.79	76.11	79.55	-	-
	G	4-β-Glcp	4.51	3.3	3.49	3.54	-	-
	G_	α-Glcp	92.40	71.85	-	-	-	-
	G_	α-Glcp	5.21	3.57	3.82	3.64	3.94	3.86
	G_	β-Glcp	96.34	74.44	75.32	81.15	75.41	60.52
	G_	β-Glcp	4.65	3.28	3.63	3.62	3.59	3.80/3.94

G = -4)-β-D-Glcp-(1-

S = α-L-Araf-(1-2)-a-D-Xylp-(1-6)-β-D-Glcp-(1-

L = β-D-Galp-(1-2)-a-D-Xylp-(1-6)-β-D-Glcp-(1-

X = a-D-Xylp-(1-6)-β-D-Glcp-(1-

G: -4)-β-D-Glcp-(1-

G_: Reducing end glucose

_G: Non-reducing end glucose

Table 1. 13C NMR and 1H NMR chemical shifts (δ in ppm) for cranf1b-F2.