Table 4.
13C NMR data of pyridoacridine alkaloids 20–26.
| Position | (125 MHz, DMSO-d6) | (100 MHz, DMSO-d6) | (100 MHz, CDCl3) | ||||
| 20 [42] | 21 [40] | 22 [40] | 23 [46] | 24 [53] | 25 [54] | 26 [55] | |
| 1 | 117.5 | 115.8 | 116.0 | 117.3 | 116.3 | 132.0 | 131.5 |
| 2 | 135.3 | 131.1 | 131.5 | 134.4 | 131.8 | 131.8 | 130.1 |
| 3 | 123.0 | 120.4 | 120.7 | 122.5 | 120.8 | 131.6 | 128.3 |
| 4 | 125.5 | 123.4 | 123.7 | 127.1 | 123.5 | 124.0 | 123.0 |
| 4a | 114.1 | 115.5 | 115.7 | 114.6 | 115.8 | 122.5 | 122.1 |
| 4b | 148.5 | 139.0 | 139.3 | 152.4 | 139.4 | 140.5 | 138.2 |
| 5 | 107.6 | 107.9 | 108.2 | 107.9 | 108.4 | 117.2 | 114.7 |
| 6 | 142.7 | 150.4 | 150.6 | 144.8 | 150.9 | 149.1 | 149.9 |
| 7a | 131.8 | 143.1 | 143.7 | nd | 143.5 | 152.0 | 149.5 |
| 7b | 132.7 | 140.1 | 140.5 | 135.3 | 140.7 | 140.7 | 142.0 |
| 8 | – | – | – | – | – | – | – |
| 9 | 153.8 | 148.4 | 148.6 | 151.0 | 148.9 | 162.1 | 154.6 |
| 10a | 143.2 | 139.1 | 139.3 | 144.0 | 140.0 | 146.3 | 148.3 |
| 11 | 108.4 | 104.3 | 104.5 | 107.4 | 106.0 | 72.5 | 74.1 |
| 11a | 132.8 | nd | 133.3 | 133.0 | 133.8 | 162.7 | 161.5 |
| 11b | 118.3 | 117.4 | 117.6 | 118.2 | 117.9 | 115.5 | 114.0 |
| 12a | 140.5 | 139.5 | 139.7 | 140.3 | 139.6 | 146.5 | 144.9 |
| 13 | 31.0 | 30.6 | 30.9 | 31.0 | 34.6 | 47.2 | 47.4 |
| 14 | 36.2 | 36.0 | 36.2 | 36.8 | 39.6 | 41.5 | 35.2 |
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| C=O | 167.8 | 176.9 | 176.8 | 169.9 | – | 174.3 | 173.6 |
| – | 118.1 CH | 33.6 CH | 41.1 CH | 131.0 C | – | 39.9 CH | 29.4 CH2 |
| – | 150.3 C | 19.1 CH3 | 26.5 CH2 | 130.7 CH | – | 26.3 CH3 | 9.5 CH3 |
| – | 26.8 CH3 | 19.1 CH3 | 17.1 CH3 | 13.7 CH3 | – | 26.3 CH3 | – |
| – | 19.5 CH3 | – | 11.5 CH3 | 12.4 CH3 | – | – | – |





