Table 2.
Entry | Substrates | Product | Catalyst (mol %) | GC Yield (selectivity) [%] | E/Z |
1b | nG (0.4) | 84 (99) | 6/1 | ||
nG-I2 (0.4) | 88 (96) | 4.8/1 | |||
nG-SIPr (0.4) | 88 (98) | 5/1 | |||
nG-SIPr-I2 (0.4) | 84 (90) | 3/1 | |||
2c | nG (0.5) | 98 (>99) | 19/1 | ||
nG-I2 (0.5) | 74 (88) | 9/1 | |||
nG-SIPr (0.5) | 98 (>99) | 9/1 | |||
nG-SIPr-I2 (0.5) | 30 (44) | 9/1 |
aToluene, 0.2 M, 70 °C, 2 h; b3 equiv of 13; c3 equiv of 15.