Table 4.
RCM with commercially available catalysts in technical grade solvents.a
![]() | ||||||
| GC yield (%) | ||||||
| Catalyst | T (°C) | AcOEt | DMC | CPME | 2-MeTHF | DCM/tolueneb |
| 15 | 40 | 97 | 98 | 80 | 35 | 92 |
| 70 | 98 | 98 | 97 | 95 | 67 | |
| 87 | 40 | 94 | 85 | 79 | 49 | 96 |
| 70 | 98 | 98 | 97 | 65 | 65 | |
| 88 | 40 | 66 | 79 | 20 | 37 | 98 |
| 70 | 99 | 98 | 60 | 65 | 61 | |
| 84 | 40 | 96 | 98 | 69 | 38 | 93 |
| 70 | 98 | 98 | 95 | 92 | 59 | |
| 89 | 40 | 88 | 98 | 85 | 84 | 91 |
| 70 | 99 | 98 | 92 | 97 | 98 | |
| 91 | 40 | 96 | 99 | 97 | 97 | 88 |
| 70 | 99 | 99 | 99 | 99 | 99 | |
| 92 | 40 | 98 | 99 | 97 | 97 | 91 |
| 70 | 99 | 99 | 99 | 98 | 99 | |
| 86 | 40 | 92 | 98 | 89 | 93 | 95 |
| 70 | 94 | 98 | 84 | 98 | 96 | |
aReaction conditions: Cat. 0.25 mol %, nondegassed, undistilled ACS grade solvents in air (0.1 M), 1 h. DMC: dimethyl carbonate; CPME: cyclopentyl methyl ether; 2-MeTHF: 2-methyltetrahydrofuran.bDCM was used at 40 °C while toluene at 70 °C [62].
