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. 2015 Oct 30;11:2038–2056. doi: 10.3762/bjoc.11.221

Table 4.

RCM with commercially available catalysts in technical grade solvents.a

graphic file with name Beilstein_J_Org_Chem-11-2038-i017.jpg

GC yield (%)
Catalyst T (°C) AcOEt DMC CPME 2-MeTHF DCM/tolueneb

15 40 97 98 80 35 92
70 98 98 97 95 67
87 40 94 85 79 49 96
70 98 98 97 65 65
88 40 66 79 20 37 98
70 99 98 60 65 61
84 40 96 98 69 38 93
70 98 98 95 92 59
89 40 88 98 85 84 91
70 99 98 92 97 98
91 40 96 99 97 97 88
70 99 99 99 99 99
92 40 98 99 97 97 91
70 99 99 99 98 99
86 40 92 98 89 93 95
70 94 98 84 98 96

aReaction conditions: Cat. 0.25 mol %, nondegassed, undistilled ACS grade solvents in air (0.1 M), 1 h. DMC: dimethyl carbonate; CPME: cyclopentyl methyl ether; 2-MeTHF: 2-methyltetrahydrofuran.bDCM was used at 40 °C while toluene at 70 °C [62].