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. 2015 Oct 30;11:2038–2056. doi: 10.3762/bjoc.11.221

Table 5.

RCM and ene–yne reactions catalysed by 93a–f and 94 in air.a

Substrate Productb Catalyst (mol %) T (°C)c t (h) Yield (%)d
Inline graphic
29 		Inline graphic
30 		85 (1)
93a (1)
93b (1)
93c (1)
93d (1)
93e (1)
93f (1)
94 (1)		 30
30
30
30
30
30
30
30		 0.4
1.7
1.7
1.7
1.8
1.7
1.9
0.9		 42
96
93
7
92
97
17
90
Inline graphic
77 		Inline graphic
78 		85 (1)
93a (1)
93b (1)
93d (1)
93e (1)		 30
30
30
30
30		 1.7
1.7
1.5
1.7
1.5		 23
87
72
72
86
Inline graphic
95 		Inline graphic
96 		85 (5)
93a (5)
93b (5)
93d (5)
93e (5)		 30
30
30
30
30		 0.4
0.4
0.4
0.4
0.4		 40
41
38
36
35
Inline graphic
55 		Inline graphic
56 		85 (2)
93a (2)
93b (2)		 30
30
30		 6
5
8		 94e
96e
96e

aReaction conditions: Catalyst (mol %), nondegassed DCM (commercial-grade HPLC) (0.1 M) in air. bE = COOEt. cReactions at 50 °C were performed in nondegassed toluene (commercial-grade HPLC) in air. dYields determined by 1H NMR. eIsolated yields after flash chromatography [83].