Skip to main content
. Author manuscript; available in PMC: 2016 Jul 6.
Published in final edited form as: Adv Synth Catal. 2015 Jul 14;357(10):2339–2344. doi: 10.1002/adsc.201500334

Table 5.

Pd-Catalyzed carboamination reactions between phenyl triflate and N-trifluoroacetyl-pent-4-enylamine.[a]

graphic file with name nihms735241f8.jpg
[a]

Conditions: 1.0 equiv 8, 1.2 equiv PhOTf, 1.4 equiv LiOtBu, 2 mol % Pd(OAc)2, PhCF3, 100 °C. Yields are isolated yields (average of two experiments).

[b]

The reaction was conducted using 2 equiv PhOTf, 4 mol % Pd(OAc)2 and 10 mol % CPhos.