. 2015 Nov 9;119(48):27162–27172. doi: 10.1021/acs.jpcc.5b08827

Table 1. Adsorption Distances, d_X, of the Atomic Species, X ∈ {H,C,O,F}, Relative to the Relaxed Uppermost Metal Layer and Adsorption Energies, E_ads, for Homogeneous Monolayers of TFBQ and TFBD on Cu(111) and Ag(111) at Full Coverage^a.

adsorbate	surface	d_H [Å]	d_C [Å]	d_O [Å]	d_F [Å]	E_ads [eV]
TFBD	Cu(111)	2.89	3.03	3.06	3.07	–0.9
TFBD	Ag(111)	2.86	3.09	3.05	3.12	–0.9
TFBQ	Cu(111)	-	2.30	2.10	2.60	–2.6
TFBQ	Ag(111)	-	2.83	2.46	2.85	–1.5

On Ag the topmost metal layer relaxed inward by 4 and 5 pm for adsorption of TFBD and TFBQ, respectively; for Cu the shifts are smaller than 1 pm.

Table 1. Adsorption Distances, dX, of the Atomic Species, X ∈ {H,C,O,F}, Relative to the Relaxed Uppermost Metal Layer and Adsorption Energies, Eads, for Homogeneous Monolayers of TFBQ and TFBD on Cu(111) and Ag(111) at Full Coveragea.