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. Author manuscript; available in PMC: 2016 Oct 21.
Published in final edited form as: Tetrahedron Lett. 2015 Oct 21;56(43):5870–5873. doi: 10.1016/j.tetlet.2015.09.002

Table 1.

The ring expansion products (3a–g) from the corresponding ketones (4a–g).

Entry Starting Ketone (4) Acyloxy nitroso Compound (2) Product (3) % Yield
a graphic file with name nihms723891t1.jpg graphic file with name nihms723891t2.jpg graphic file with name nihms723891t3.jpg 25
b graphic file with name nihms723891t4.jpg graphic file with name nihms723891t5.jpg graphic file with name nihms723891t6.jpg 77
c graphic file with name nihms723891t7.jpg graphic file with name nihms723891t8.jpg graphic file with name nihms723891t9.jpg 71
d graphic file with name nihms723891t10.jpg graphic file with name nihms723891t11.jpg graphic file with name nihms723891t12.jpg 12
e graphic file with name nihms723891t13.jpg graphic file with name nihms723891t14.jpg graphic file with name nihms723891t15.jpg 63
f graphic file with name nihms723891t16.jpg graphic file with name nihms723891t17.jpg graphic file with name nihms723891t18.jpg 67
g graphic file with name nihms723891t19.jpg graphic file with name nihms723891t20.jpg graphic file with name nihms723891t21.jpg 81