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. 2015 Sep 11;54(45):13362–13365. doi: 10.1002/anie.201505949

Figure 1.

Figure 1

ORTEP representations of the compounds 1 (a) and 2 (b; 30 % probability ellipsoids). Isopropyl methyl groups and hydrogen atoms omitted for clarity. Selected bond lengths [Å] and angles [°]: (1) Mg1–O2 2.3737(18), Mg1–N3 2.003(2), O2–B1 1.418(3), B1–N3 1.379(4), N3–C30 1.423(3); N1-Mg1-N2 94.72(8), Mg1-O2-B1 80.94(14), O2-B1-N3 116.8(2), B1-N3 Mg1 96.96(15), B1-N3-C30 120.6(2); (2) Mg1–B1 2.3092(15), Mg1–O1 2.0556(9), Mg1–H1a 1.932(14), Mg1–H1b 1.929(15), B1–C35 1.618(2), B1–C39 1.6026(19); N1-Mg1-N2 93.48(4), N1-Mg1-B1 125.62(5), C35-B1-C39 107.44(11).