Table I. Chemical composition of trichomes from Stevia.
| No.a | Compounds | RTb | RIc | Formula | RAd |
|---|---|---|---|---|---|
| min | % | ||||
| 1 | α-Pinene | 9.07 | 922 | C10H16 | 0.13 |
| 2 | (+)-Sabinene | 9.74 | 972 | C10H16 | 0.15 |
| 3 | β-Pinene | 9.84 | 979 | C10H16 | 1.10 |
| 4 | β-Linalool | 11.82 | 1,126 | C10H18O | 0.17 |
| 5 | l-α-Terpineol | 13.49 | 1,186 | C10H18O | 0.06 |
| 6 | β-Elemene | 16.82 | 1,389 | C15H24 | 1.84 |
| 7 | Caryophyllene | 17.37 | 1,424 | C15H24 | 2.15 |
| 8 | α-Bergamotene | 17.45 | 1,432 | C15H24 | 0.94 |
| 9 | α-Humulene | 17.89 | 1,452 | C15H24 | 1.18 |
| 10 | Germacrene D | 18.29 | 1,484 | C15H24 | 1.10 |
| 11 | β-Selinene | 18.40 | 1,489 | C15H24 | 0.29 |
| 12 | Elixene | 18.52 | 1,492 | C15H24 | 1.27 |
| 13 | γ-Cadinene | 18.74 | 1,513 | C15H24 | 0.24 |
| 14 | δ-Cadinene | 18.82 | 1,524 | C15H24 | 0.17 |
| 15 | (±)-trans-Nerolidol | 19.27 | 1,561 | C15H26O | 0.93 |
| 16 | Farnesol | 19.47 | 1,620 | C15H26O | 0.17 |
| 17 | Germacrene d-4-ol | 19.69 | 1,660 | C15H26O | 0.56 |
| 18 | α-epi-Cadinol | 20.58 | 1,638 | C15H26O | 0.27 |
| 19 | α-Cadinol | 20.79 | 1,652 | C15H26O | 0.28 |
| 20 | Isoaromadendrene epoxide | 21.08 | 1,579 | C15H24O | 0.40 |
| 21 | Ledene oxide-(II) | 22.18 | 1,683 | C15H24O | 0.09 |
| 22 | [2-(4-Methoxy-phenyl)-[1,3]dioxolan-2-yl]-acetic acid | 23.46 | 1,930 | C12H14O5 | 0.15 |
| 23 | Manoyl oxide | 25.32 | 1,988 | C20H34O | 1.07 |
| 24 | n-Octadecanol | 25.95 | 2,053 | C18H38O | 2.39 |
| 25 | Ethanol, 2-[2-[4-(1,1,3,3-tetramethylbutyl)phenoxy]ethoxy]- | 26.93 | 2,126 | C18H30O3 | 0.28 |
| 26 | Stearyl acetate | 27.30 | 2,160 | C20H40O2 | 0.33 |
| 27 | 3-Oxomanoyl oxide | 27.90 | 2,219 | C20H32O2 | 2.73 |
| 28 | (+)-Agathadiol | 28.80 | 2,357 | C19H30O2 | 4.80 |
| 29 | (+)-Copaiferic acid | 28.96 | 2,369 | C20H32O2 | 4.62 |
| 30 | 4,8,13-Duvatriene-1,3-Diol | 29.28 | 2,400 | C21H28O2 | 0.72 |
| 31 | 4-(3-Hydroxy-3-methylpentyl)-3,4a,8,8-tetramethyldecahydro-1-naphthalenol | 29.57 | 2,415 | C20H34O2 | 1.30 |
| 32 | Androstan-17-one, 3-methoxy-16,16-dimethyl-, (3β,5α)- | 29.86 | 2,418 | C22H36O2 | 1.90 |
| 33 | Labda-8(20),13-dien-15-oic acid, 19-hydroxy-, methyl ester, (E)- | 30.45 | 2,429 | C21H32O3 | 29.64 |
| 34 | Pregnane-18,20-diol, (5α)- | 31.09 | 2,449 | C21H36O2 | 5.63 |
| 35 | Allopregnane-3α,20α-diol | 31.47 | 2,475 | C21H36O2 | 12.20 |
| 36 | 17-α-Hydroxypregnenolone | 31.57 | 2,480 | C20H32O2 | 9.97 |
| 37 | 2-[5-(2,2-Dimethyl-6-methylene-cyclohexyl)-3-methyl-pent-2-enyl]-[1,4]benzoquinone | 31.84 | 2,489 | C21H28O2 | 2.91 |
| 38 | Isophthalic acid, 3,7-dimethyloct-6-enyl propyl ester | 31.96 | 2,492 | C21H30O4 | 3.30 |
| 39 | 3-Ethyl-5-(2'-ethylbutyl)octadecane | 32.13 | 2,599 | C26H54 | 0.76 |
| 40 | Allopregnane-7α,11α-diol-3,20-dione | 32.36 | 2,613 | C21H32O4 | 0.39 |
| 41 | Ethanol, 2-[2-[2-[2-[p-(1,1,3,3-tetramethylbutyl)phenoxy]ethoxy]ethoxy]ethoxy]- | 32.64 | 2,676 | C22H38O | 0.97 |
| 42 | n-Heptacosane | 33.06 | 2,700 | C27H56 | 0.45 |
Compound listed in order of elution in an HP-5MS Ultra Inert (UI) column.
Retention time.
Retention indices calculated against C7-C30 n-alkanes on the HP-5MS UI column.
Relative amount. Ratio expressed against the sum of all peaks.