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. 2015 Mar 3;54(16):4895–4898. doi: 10.1002/anie.201411852

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© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

© 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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scheme 1 — a)Catalytic asymmetric addition reactions of isocyanoacetate pronucleophiles to carbonyl or imine electrophiles. b)Aminophosphine/silver(I) binary catalyst system applied in this work.