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. Author manuscript; available in PMC: 2017 Jan 4.
Published in final edited form as: Chem Commun (Camb). 2016 Jan 4;52(1):108–111. doi: 10.1039/c5cc07780j

Table 3.

Benzylic acid rearrangement reactions leading to 1H-pyrrol-3(2H)-ones.a

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a

Reaction conditions:3 (0.10 mmol), 5 (0.11 mmol), DCM (0.50 mL), CF3COOH (20 mol%), 65 °C, 24 h; Yields refer to isolated yields after column chromatography; The ee value was determined by HPLC using a chiral stationary phase.