Table 1. Experimental Conditions and Initial Nonstoichiometries of Ceria Pellets for Performing Raman Spectroscopy of Surface.
reduction methodology | none | chemical pH2 = 0.02 atm | chemical pH2 = 0.02 atm | thermal pO2 ≪ 1 atm | thermal pO2 ≪ 1 atm |
---|---|---|---|---|---|
Tred (K) | – | 1373 | 1373 | 1773 | 1773 |
duration (min) | – | 0 | 120 | 5 | 180 |
δi (−) | 0 | 0.128 | 0.253 | 0.034 | 0.057 |