Table 3.
Distribution of products observed in the reactions of benzyl persulfide as measured by integration of the peaks present in the product spectra. The polysulfides were identified using their reported chemical shifts.[38]
| Reactant | BnSH | BnSSBn | BnS3Bn | BnS5Bn | BnS6Bn |
|---|---|---|---|---|---|
| PPh3 | 0.54 | 0.07 | 0.39 | - | - |
| [Na+][TrtS−] | 0.41 | - | 0.30 | 0.22 | 0.07 |
| [NBu4+][HS−] | - | - | 0.58 | 0.33 | 0.09 |
| [NBu4+][CN−] | 0.28 | 0.15 | 0.37 | 0.14 | 0.06 |
| [NBu4+][AcO−] | 0.26 | 0.08 | 0.48 | 0.18 | - |
| [NBu4+][Cl−] | - | - | 0.61 | 0.28 | 0.11 |
| [NBu4+][I−] | - | - | 0.5 | 0.35 | 0.15 |
| NEt3 | 0.28 | 0.03 | 0.39 | 0.21 | 0.09 |