Table 1. Grafting densities (chains nm−2) of polystyrene ligands on Au NCs estimated from TGA.
Core diameter | OLAM | PS-SH (1.1 k) | PS-SH (1.5 k) | PS-SH (3.0 k) | PS-SH (5.0 k) | PS-SH (11.5 k) | PS-SH (20.0 k) |
---|---|---|---|---|---|---|---|
3.8 nm Au | 5.60 | 2.62 | — | 2.25 | 1.71 | 1.08 | — |
4.5 nm Au | 5.75 | 2.16 | — | 2.28 | 1.89 | — | — |
7.6 nm Au | 4.92 | — | 2.39 | 1.79 | 1.27 | 0.95 | 0.83 |
OLAM, oleylamine; PS-SH, thiol-terminated polystyrene; TGA, thermal gravimetric analysis.
The estimated error is less than 10% based on multiple runs with the same sample.