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Influence of bulk solution pD on kobs of amide HDX. Varying the presence and type of guest affords order-of-magnitude changes in kobs, whose minimum pD values are shifted up to 6 pD units relative to poly-DL-alanine (PDLA). Lines represent fits of experimental kobs values to Eq. 2 (Fig. 7D; see Table 1 for rate constants).
