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. Author manuscript; available in PMC: 2016 Oct 14.
Published in final edited form as: J Am Chem Soc. 2015 Sep 29;137(40):13066–13071. doi: 10.1021/jacs.5b08019

Scheme 1.

Scheme 1

Dual ruthenium-based catalytic cycles wherein al-kyne-to-allene isomerization occurs in tandem with redox-triggered C-C bond formation.a

aArSO3H = 2,4,6-(2-Pr)3PhSO3H.