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Logarithmic correlation between values of kcat for yTIM catalyzed isomerization of GAP and the intrinsic dianion binding energy for phosphite dianion activation of wildtype and mutant TIM-catalyzed reactions of [1-13C]-GA. Key: green symbols, mutants of TIM from T. brucei (TbbTIM); blue symbols, mutants of TIM from chicken muscle (cTIM); red symbols, mutants of yTIM.
