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. Author manuscript; available in PMC: 2016 Jun 19.
Published in final edited form as: J Org Chem. 2015 Jun 1;80(12):6012–6024. doi: 10.1021/acs.joc.5b00794

Table 7.

Visible-Light Photocatalytic Allylic and Vinylic Substitution Reactions of N-phthalimidoyl Oxalate 3aa

Entry Acceptor Product Yield
(%)b
1 graphic file with name nihms-746869-t0009.jpg 69
2 graphic file with name nihms-746869-t0010.jpg ND
3 graphic file with name nihms-746869-t0011.jpg 35c
(E/Z >
20:1)
4 graphic file with name nihms-746869-t0012.jpg 47
5 graphic file with name nihms-746869-t0013.jpg 19c
(E/Z >
20:1)
6 graphic file with name nihms-746869-t0014.jpg 42
(dr 1:1)
a

Reaction conditions of Table 6, entry 1.

b

Isolated yield after silica gel chromatography (average of two experiments).

c

5 equiv of the acceptor and 1 equiv of the oxalate were used.

ND = not detected.