Skip to main content
. Author manuscript; available in PMC: 2016 Jun 3.
Published in final edited form as: J Am Chem Soc. 2015 May 20;137(21):6742–6745. doi: 10.1021/jacs.5b03091

Figure 2.

Figure 2

Results from evaluation of 58 ligands for the asymmetric silylation of diarylmethyl silyl ethers 2a and 2j (% ee). Conditions: [Rh(cod)Cl]2 (2.5 mol %), ligand (5 mol %), nbe (2 equiv), THF, 50 °C. Selected ligand categories: Josiphos class (L1–L12), Walphos class (L15–L22), Segphos class (L30–L33), and catASium class (L46, L47).