Table 1. The composition (in % according to GC) of products mixture after 5 days of enzymatic oxidation of racemic decane-1,4-diol (1a).

Enzyme	OXIDATION CONDITIONS								Substrate	Products
	Coenzyme		Temperature[°C]			pH			1a	2a and 3a	4a
	NAD+/ NADP+	FMN	25	35	45	7.2	8.5	9.0	[%]	[%]	[%]	ee [%]
HLADH	√	√	√					√	4	4	92	22 (–)-(S)
HLADH*	√	√	√					√	nd	nd	100	0
	√	√		√			√		nd	nd	100	0
	√	√	√			√			83	nd	17	20 (–)-(S)
	√		√					√	32	1	67	22 (–)-(S)
BSADH	√		√					√	89	2	9	-
	√	√			√			√	98	nd	2	-
LKADH	√	√	√			√			100	nd	nd
	√	√	√				√		95	1	4	-
PADH I	√	√	√			√			60	nd	40	26 (–)-(S)
	√	√	√				√		100	nd	nd
PADH II	√	√	√			√			91	8	1	-
	√	√	√				√		62	2	36	18 (–)-(S)
PADH III	√	√	√			√			59	18	23	53 (+)-(R)
	√	√	√				√		nd	41	59	48 (+)-(R)
YADH	√	√	√			√			90	4	6	10 (+)-(R)
	√	√	√				√		88	nd	12	8 (+)-(R)

*alcohol dehydrogenase recombinant from E. coli (HLADH); ee-enantiomeric excess; nd-not detected