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. 2016 Jan 7;11(1):e0146160. doi: 10.1371/journal.pone.0146160

Table 3. The composition (in % according to GC) of products mixture after 5 days of enzymatic oxidation of racemic decane-1,5-diol (1b).

Enzyme OXIDATION CONDITIONS Substrate Products
Coenzyme Temperature[°C] pH 1b 2b and 3b 4b
NAD+/ NADP+ FMN 25 35 45 7.2 8.5 9.0 [%] [%] [%] ee [%]
HLADH 9 41 50 46 (+)-(R)
HLADH* 23 36 41 30 (+)-(R)
30 49 21 38 (+)-(R)
58 17 25 50 (+)-(R)
62 29 9 48 (+)-(R)
BSADH 68 29 3 -
98 2 nd
LKADH 100 nd nd
100 nd nd
PADH I 90 10 nd
100 nd nd
PADH II 83 9 8 -
81 14 5 -
PADH III 77 23 nd
68 32 nd
YADH 100 nd nd
100 nd nd

*alcohol dehydrogenase recombinant from E. coli (HLADH); ee-enantiomeric excess; nd-not detected