Table 1.
Cu–S | Cu–N(His) | Cu–S(Met) | |||||||||
Sample/Fit | F | N | R, Å | DW, Å2 | N | R, Å2 | DW, Å | N | R, Å2 | DW, Å | E0 |
Cu(I)-WTAz | 0.00039 | 1 | 2.19 | 0.002 | 2 | 1.97 | 0.010 | 1 | 2.68 | 0.003 | −0.231 |
Cu(I)-HPAz (pH 6.5) | 0.00022 | 1 | 2.17 | 0.004 | 1 | 1.92 | 0.010 | −0.387 | |||
Cu(I)-HPAz (pH 8) | 0.00023 | 1 | 2.17 | 0.003 | 1.3 | 1.93 | 0.003 | −0.591 | |||
Cu(II)-WTAz | 0.00051 | 1 | 2.17 | 0.003 | 2 | 1.93 | 0.008 | 1 | 2.70 | 0.006 | −2.346 |
Cu(II)-HPAz | 0.00056 | 1 | 2.23 | 0.010 | 2 | 1.98 | 0.005 | −2.905 |