Table 5.
Mass spectrometric parameters used for the determination of the mycotoxins.
| Analyte | Precursor Ion (DP) | Quantifier (CE; CXP) | Qualifier (CE; CXP) |
|---|---|---|---|
| deoxynivalenol | 355.1 (−40) | 59.2 (−40; −8) | 265.2 (−22; −13) |
| 3-acetyl-deoxynivalenol | 397.3 (−40) | 59.2 (−38; −8) | 307.1 (−20; −7) |
| 15-acetyl-deoxynivalenol | 397.3 (−40) | 59.2 (−38; −8) | 337.1 (−10; −7) |
| nivalenol | 371.1 (−45) | 59.1 (−42; −7) | 281.1 (−22; −15) |
| fusarenon X | 413.3.(−40) | 59.1 (−40; −9) | 262.9 (−22; −16) |
| HT-2 toxin | 442.2 (46) | 263.1 (21; 19) | - |
| 447.4 (101) | - | 345.1 (27; 20) | |
| T-2 toxin | 484.3 (56) | 215.2 (29; 18) | 185.1 (31; 11) |
| T-2 tetraol | 316.2 (31) | 215.3 (13; 16) | 281.4 (13; 8) |
| T-2 triol | 400.2 (41) | 215.2 (17; 12) | 281.3 (13; 16) |
| NX-2 | 383.1 (−45) | 59.0 (−36; −7) | 323 (−14; −7) |
| NX-3 | 341.1 (−50) | 59.0 (−36; −7) | 281 (−14; −7) |
DP, declustering potential; CE, collision energy; CXP, cell exit potential.