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. 2015 Dec 18;1(11):e1500421. doi: 10.1126/sciadv.1500421

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Copyright © 2015, The Authors

This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license, which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.

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Fig. 2 — (A) Experimental H₂ and N₂ isotherms. (B) CO₂ adsorption isotherms carried out on 1 at different temperatures (filled circles, adsorption; open circles, desorption). For CO₂ at 195 K, the simulated adsorption isotherm is shown. (C) HOA for CO₂ in 1 as a function of the CO₂ loading determined from a virial fit to isotherms collected at temperatures ranging from −25° to 30°C. HOA determined from GCMC simulations at 25°C are also shown. (D) Experimental and simulated gas adsorption isotherms for CO₂ at 298 K (0 to 10 bar).