Skip to main content
. Author manuscript; available in PMC: 2016 Jul 15.
Published in final edited form as: J Am Chem Soc. 2015 Jul 6;137(27):8838–8850. doi: 10.1021/jacs.5b04844

Figure 6.

Figure 6

TS arrangements of aldehyde substituent axial, down and crotyl methyl group equatorial for reaction (1). Free energies relative to TS-1(3R,4R). M06/SDD-6-311G(d,p)-IEFPCM(acetone)//B3LYP/SDD-6-31G(d). Non-critical hydrogen atoms omitted for clarity. All energies in kcal mol−1.