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AGP‐catalyzed phosphorylation of different acceptor substrates (200 mm) from αGlc 1‐P (20 mm). Product yield was determined at a αGlc 1‐P conversion of ≥90 %, except for [a] 38 %, [b] 81 %, [c] 69 %, [d] 86 %, [e] 89 % and [f] 75 %. The asterisk (*) indicates the total amount of sugar 1‐phosphate products (GlcNH2 1‐P, GlcNH2 6‐P), which was used to calculate the yield.
