Design of a consensus collagen triple-helical peptide. (A)
Table of collagenous peptide sequences used in solid-phase binding
experiments. Collagen Toolkit peptides are identified by their numbers
from Toolkits II and III, whereas derivative peptides are identified by
their laboratory reference numbers. The consensus motifs, GXOGPXGFX or
GAOGASGDR, are shown in black or red font, and segments of sequence that
surround them are shown in gray. Not shown are the N- and C-terminal
flanking motifs, GPC[GPP]5- and -[GPP]5GPC-amide,
which are present on each peptide. Gpp10 denotes the control,
GPC[GPP]10GPC-amide. (B) Polarimetry data of peptide
DB316, Acetyl-GPOGPOGPOGPAGFOGPOGPO-amide were collected from 10°C
to 70°C (up to 50°C is shown) at a ramp rate of 1°C
min−1 as described in the supplemental Methods.
First derivative of the original optical rotation data were used to
define the peptide Tm. (C) Solid-phase binding of recombinant
OSCAR (ectodomain E coli– or
HEK293EBNA-expressed, 0.1 µg per well) on the collagenous peptides
listed in panel A. Each peptide/protein combination was tested in
triplicate, as described in supplemental Methods, and the inert peptide,
(GPP)10, and BSA were used as negative controls. Data
shown are mean ± SEM. (D) Biosensor curves of increasing
concentrations of E coli–expressed recombinant
OSCAR ectodomain titrated onto SRU 96-well plate coated by DB80, NR338,
II-26, as well as (GPP)10 as negative control. Each point was
collected in triplicate, and each data set was fitted to a model of
specific and nonspecific binding in GraphPad Prism. The nonspecific
binding curves were then removed for clarity. (E) Analytical gel
filtration of recombinant OSCAR ectodomain preincubated with DB316 in
different molar ratios. Each curve was derived separately using a
Superdex 75 10/300gl column, running at 0.2 mL per minute, as described
in supplemental Methods, and superimposed into 1 figure. Bmax, maximum
binding; deg, degrees; dOR/dT, rate of change of optical rotation with
temperature; ELISA, enzyme-linked immunosorbent assay; mAU, milli
absorbance units; OD, optical density; PWV, peak wavelength; SEM,
standard error of the mean.