Table 1. Photoluminescence Lifetime, τ, Quantum Yield, QY, Radiative Rate, Γr, and Non-Radiative Rate, Γnr, for the Five Compoundsa.
molecule | τ (ps) | QY | Γr (ns–1) | Γnr (ns–1) |
---|---|---|---|---|
c-P6·T6 | 627 | 0.7% | 0.010 | 1.60 |
c-P6x·T6 | 682 | 1.3% | 0.019 | 1.45 |
sEt-P11·(T6)2 | 271 | 0.5% | 0.020 | 3.73 |
s-P11·(T6)2 | 343 | 0.8% | 0.024 | 2.90 |
l-P6·T6 | 364 | 2.3% | 0.064 | 2.69 |
Details of measurements are given in the Supporting Information.