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. 2016 Feb 15;6:21530. doi: 10.1038/srep21530

Table 3. Comparison of current work and relevant reports on the functionalization of graphene and proposed enhancement mechanism.

Ref. Species and method for functionalizing graphene Synthesis method for catalysts Mechanism for the enhanced performance
27 Pulsed galvanostatic electrodeposition Synergistic effects
28 Magnetron sputtering Porous honeycomb-like structure; Large surface area; Enhanced interactions
29 Chemical reduction Bifunctional effect between Pt NPs and remaining oxygenated groups on graphene
30 Nitrogen-doped; Chemical reduction Chemical reduction Smaller particle size; Modulated electronic properties of Pt
31 Boron-doped; Thermal annealing Microwave-assisted polyol process Uniform deposition of Pt NPs; Lower d-band center
32 Nitrogen-doped; Hydrothermal Hydrothermal Smaller particle size; Stronger binding energy between Pt and N-doped graphene
33 Nitrogen-doped and ZrO2-decorated; Atomic layer deposition Chemical reduction Unique structure
34 Nitrogen-doped; Ultrosonic cavitation assisted hydrogen implosion Chemical reduction Enhanced electronic conductivity; Special structure
Current work Grafted with taurine molecules; One-pot method Self-assembly Smaller particle size and uniform distribution; Lower d-band center; Enhanced charge transfer ability