Table 1. Selected examples for zero-field splitting parameters.
| Compound | D (cm–1) | Ueff (cm–1) | Literature |
|---|---|---|---|
| (Ph4P)2[Co(C3S5)2] | –161 | 33.9 | Fataftah et al.19 |
| (HNEt3)2[Co(pdms)2] | –115 | 118 | * |
| (Ph4P)2[Co(SePh)4] | –83 | 19.1 | Zadrozny et al.20 |
| [Co(AsPh3)2(I)2] | –74.7 | 32.6 | Saber et al.21 |
| [Co(salbim)2] | +67 | — | Šebová et al.22 |
| (Ph4P)2[Co(SPh)4] | –62 | 21.1 | Zadrozny et al.20 |
| [Co{NtBu)3SMe}2] | –58 | 75† | Carl et al.24 |
| [Co(acac)2(H2O)2] | +57 | — | Gómez-Coca et al.23 |
Reported zero-field splitting D-values with |D|>50 cm−1 and relaxation energy barriers Ueff of tetrahedral cobalt(II) complexes.
*This work
†In a 1,500 Oe applied magnetic field.