Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Synthesis of [Mn(PyC3A)(H2O)]- (a) substoicheometric benzyl bromide, dioxane, RT; (b) 3 equiv. tbutyl-bromoacetate, 1 equiv. KI, DIPEA, DMF, RT; (c) 1 atm H2 (g), 10% by wt. Pd/C, MeOH; (d) picolyl chloride, KI, DIPEA, DMF, RT; (e) 1:1 CH2Cl2:TFA, RT; (f) MnCl2, pH 6.5.
