Solid-state molecular structures for (a) [(tBuL)FeCl]2 (2), (b) (tBuL)FeCl(•NC6H3-2,6-iPr2) (3), (c) (tBuL)FeCl(H2NC6H3-2-iPr2-6-C(CH2) (CH3)) (4), and (d) [(tBuL)FeCl]2(μ-NC6H3-3,5-(CF3)2) (6) with thermal ellipsoids at 50% probability level. Color scheme: Fe, orange; N, blue; Cl, aquamarine; F, green. Hydrogens, solvent molecules, and disordered isopropyl group in 3 are omitted for clarity.