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. Author manuscript; available in PMC: 2016 Feb 25.
Published in final edited form as: J Am Chem Soc. 2016 Feb 4;138(6):1983–1993. doi: 10.1021/jacs.5b12582

Table 1.

Catalytic Reactivity of 2 and 3,5-Bis(trifluoromethyl)phenyl Azided

Substrate Product Yield (%)
graphic file with name nihms-759668-t0020.jpg graphic file with name nihms-759668-t0021.jpg 76a
graphic file with name nihms-759668-t0022.jpg graphic file with name nihms-759668-t0023.jpg 35a
graphic file with name nihms-759668-t0024.jpg graphic file with name nihms-759668-t0025.jpg 85a
graphic file with name nihms-759668-t0026.jpg graphic file with name nihms-759668-t0027.jpg 21b
graphic file with name nihms-759668-t0028.jpg graphic file with name nihms-759668-t0029.jpg 92c
a

Isolated yields.

b

1H NMR yield using ferrocene as internal standard.

c

19F NMR yield using 1,2-difluorobenzene as internal standard.

d

All reactions were conducted neat in substrate.