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. 2016 Feb 26;6:22234. doi: 10.1038/srep22234

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Copyright © 2016, Macmillan Publishers Limited

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(A) ECL, (B) CV and (C) EIS responses of (a) GCE, (b) Ru-SiO₂@PEI/GCE (c) Au/Ru-SiO₂@PEI/GCE, (d) anti-NSE/Au/Ru-SiO₂@PEI/GCE, (e) BSA/anti-NSE/Au/Ru-SiO₂@PEI/GCE, (f) NSE/BSA/anti-NSE/Au/Ru-SiO₂@PEI/GCE. The ECL responses were measured in 0.1 M PBS (pH 7.5); Scan rate: 100 mV s⁻¹. Scan potential: 0~1.35 V. CV and EIS were conducted in 0.1 M KCl solution containing of 5.0 mM [Fe(CN)₆]^3−/4−.