Figure 53.
Examples of solvates wherein the chlorinated solvents are pinned by XBs. For the sake of clarity, only the supramolecular anion is reported. Metal atoms are labeled. Color code: carbon, gray; oxygen, red; bromine, light brown; chlorine, light green, hydrogen, white. XBs are dotted black lines. CSD Refcodes are reported: HIDMEN, trichloro(tripyrazolylmethane-N,N′,N″)rhenium(IV) perrhenate chloroform solvate; FIYLEG, [μ2-1,1′-bis[(1,3-dimethylimidazolidin-2-ylidene)amino]ferrocene]chloropalladium hemi(tetrachloropalladium) dichloromethane solvate; VEGTIL, [N,N′-bis(2,6-diisopropylphenyl)triptycenylimidoformamidium]tetrabromoindium(II) chloroform solvate.